Start with the mathematical object
A gauge Lie algebra determines the local commutation relations. A connected group with that algebra also requires a global form. For compact simple Lie algebra, write G = G̃/Γ, with G̃ simply connected and Γ a subgroup of its center.
Test the matter representation
An irreducible representation of G̃ is an ordinary representation of G precisely when Γ acts trivially. For SU(2) → SO(3), this selects integer spin. For SU(3) → PSU(3), it selects zero triality. The workbench preserves a chosen highest weight when you change the global form, so an obstruction remains visible.
Reverse the question
Given several matter multiplets, take the intersection of their kernels in the center. Any subgroup of that intersection defines a compatible central quotient. This constrains the gauge group without selecting one quotient uniquely.
Specify the physical theory
The gauge group and the matter content are parts of the theory data. Choices of magnetic and dyonic lines and discrete theta parameters can carry additional information. A group page supplies mathematical data. The current saved physical-setup format records fields, a gauge quotient and a polynomial counting question; line spectra and theta choices require additional theory data outside that format.
Try a calculation
Select PSU(3) and enter (p,q) = (3,0). This ten-dimensional representation descends, but is of complex type. Zero center charge and reality type are independent questions.
Specify matter and the quotient
Read gauge symmetry and matter representations, then work through the Standard Model setup. Saved polynomial setups retain the selected group and matter; line-operator spectra and theta choices remain outside that format.